(E)-O-IsopropylN-(4-nitrophenyl)thiocarbamate
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چکیده
منابع مشابه
(E)-O-Isopropyl N-(4-nitrophenyl)thiocarbamate
The configuration of the thione-aryl C-N single bond in the title mol-ecule, C(10)H(12)N(2)O(3)S, is E. Centrosymmetrically related mol-ecules are connected into a dimer via an eight-membered thio-amide {⋯H-N-C=S}(2) synthon and mol-ecules are consolidated into the crystal structure via C-H⋯O inter-actions.
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In the mol-ecule of the title compound, C(15)H(15)NO(2), the aromatic rings are oriented at a dihedral angle of 15.46 (6)°. An intra-molecular O-H⋯N hydrogen bond results in the formation of a nearly planar six-membered ring [maximum deviation of 0.035 (5) Å for the N atom] which is almost coplanar with the adjacent ring, making a dihedral angle of 0.8 (3)°. The title organic mol-ecule is a phe...
متن کاملCrystal structure of (E)-1-(4-chlorophenyl)ethanone O-dehydroabietyloxime
The title compound, C28H34ClNO2 {systematic name: (E)-1-(4-chloro-phen-yl)ethanone O-[(1R,4aS,10aR)-7-isopropyl-1,4a-di-methyl-1,2,3,4,4a,9,10,10a-octa-hydro-phenanthrene-1-carbonyl]oxime}, was synthesized from de-hydro-abietic acid. In the de-hydro-abietyl moiety, the central and terminal cyclo-hexane rings display chair and half-chair conformations, respectively, and a trans-ring junction. Th...
متن کامل2-Bromo-4-chloro-6-[(E)-o-tolyliminomethyl]phenol
The title compound, C(14)H(11)BrClNO, is a Schiff base compound derived from the condensation of 3-bromo-5-chloro-salicyl-aldehyde and o-toluidine in methanol. The aromatic rings make a dihedral angle of 38.3 (1)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond, generating an S(6) ring.
متن کاملCrystal structure of (E)-1-(4-methoxyphenyl)ethanone O-dehydroabietyloxime
In the title compound, C29H37NO3 {systematic name: (E)-1-(4-meth-oxy-phen-yl)ethanone O-[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa-hydro-phenanthrene-1-carbon-yl]oxime}, a new derivative of de-hydro-abietic acid, the two cyclo-hexane rings exhibit a trans-ring junction and are in chair and half-chair conformations. The C=N double bond exhibits an E conformation.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2007
ISSN: 1600-5368
DOI: 10.1107/s1600536807067360